氢键增强酰腙动态共价键智能水凝胶的制备及性能
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刘通(1998—),男,硕士研究生,研究方向为功能高分子材料。E-mail:1328433071@qq.com

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O633

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国家自然科学基金项目(21802041,21865009);江西省杰出青年基金项目(20202ACBL214001)


Preparation and Properties of Hydrogen-Bonding Reinforced Smart Hydrogels Crosslinked with Acylhydrazone Dynamic Covalent Bonds
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    摘要:

    通过可逆加成-断裂转移自由基聚合(RAFT)制备了一系列共聚物(PDAAM-co-PNIPAM-co-Mu),其成分为含脲基嘧啶酮(UPy)基团单体(Mu)、双丙酮丙烯酰胺(DAAM)和 N-异丙基丙烯酰胺(NIPAM),利用己二酸二酰肼(ADH)和 PDAAM-coPNIPAM-co-Mu 反应,得到酰腙动态共价键交联的智能水凝胶。 通过扫描电镜(SEM)、流变仪和万能试验机对智能水凝胶的结构、力学性能以及智能特性进行了考察。 实验结果表明:UPy 基团引入到该水凝胶网络中能够通过氢键增强水凝胶,其压缩强度提高了近 4 倍;同时,该水凝胶具有 pH 和温度双重响应、自愈合性能,并且水凝胶的压缩强度在温度响应之后提高了近 30倍。

    Abstract:

    A series of PDAAM-co-PNIPAM-co-Mu copolymers were synthesized by RAFT polymerization from diacetone acrylamide (DAAM),N-isopropylacrylamide (NIPAM) and ureidopyrimidinone-containing monomer (Mu). Smart hydrogels crosslinked with acylhydrazone dynamic covalent bonds were obtained by the reaction between PDAAM-co-PNIPAM-co-Mu and adipic dihydrazide(ADH). The structure, mechanical properties and intelligent properties of intelligent hydrogel were investigated by scanning electron microscope (SEM),rheometer and universal testing machine. Due to the introduction of ureidopyrimidinone(UPy) hydrogen-bonding units into the network, the mechanical properties of the hydrogels were reinforced, and the compression strength of the hydrogel was increased by 4 times. Meanwhile, the hydrogels exhibited pH and temperature dual-responsive and self-healing properties, and the compression strength was increased by 30 times after heating.

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刘通,马伟,熊乐艳,郭赞如,章家立.氢键增强酰腙动态共价键智能水凝胶的制备及性能[J].华东交通大学学报,2023,40(2):87-94.

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  • 收稿日期:2022-04-13
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  • 在线发布日期: 2023-05-06
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